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Fmoc-Ser(Ac4Manα)-OH is a chemical compound used in the synthesis of glycopeptides, which are peptides with one or more carbohydrate molecules attached to them. It consists of the amino acid serine modified with a carbohydrate molecule called acetylated mannose alpha, and is protected at the amino terminus with a fluorenylmethyloxycarbonyl (Fmoc) group.
CAT No:CP27747
CAS No:118358-80-8
Synonyms/Alias:(2S)-2-(9H-Fluoren-9-ylmethoxycarbonylamino)-3-[(2S,3S,4S,5R,6R)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxypropanoic acid; N-[(9H-Fluoren-9-ylmethoxy)carbonyl]-3-[(2-O,3-O,4-O,6-O-tetraacetyl-alpha-D-mannopyranosyl)oxy]-L-alanine; N-alpha-(9-Fluorenylmethyloxycarbonyl)-O-(2,3,4,6-tetra-O-acetyl-alpha-D-mannopyranosyl)-L-serine (Fmoc-L-Ser(alpha-D-ManAc4)-OH); Fmoc-L-Ser(a-D-ManAc4)-OH
Chemical Name:(2S)-2-(9H-fluoren-9-ylmethoxycarbonylamino)-3-[(2S,3S,4S,5R,6R)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxypropanoic acid
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M.F/Formula | C32H35NO14 |
M.W/Mr. | 657.63 |
InChI | InChI=1S/C32H35NO14/c1-16(34)41-15-26-27(44-17(2)35)28(45-18(3)36)29(46-19(4)37)31(47-26)42-14-25(30(38)39)33-32(40)43-13-24-22-11-7-5-9-20(22)21-10-6-8-12-23(21)24/h5-12,24-29,31H,13-15H2,1-4H3,(H,33,40)(H,38,39)/t25-,26+,27+,28-,29-,31-/m0/s1 |
InChI Key | UGQPZVSWEMKXBN-YVMRMMKNSA-N |
Canonical SMILES | CC(=O)OCC1C(C(C(C(O1)OCC(C(=O)O)NC(=O)OCC2C3=CC=CC=C3C4=CC=CC=C24)OC(=O)C)OC(=O)C)OC(=O)C |
Isomeric SMILES | CC(=O)OC[C@@H]1[C@H]([C@@H]([C@@H]([C@H](O1)OC[C@@H](C(=O)O)NC(=O)OCC2C3=CC=CC=C3C4=CC=CC=C24)OC(=O)C)OC(=O)C)OC(=O)C |
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